A substance has a critical temperature Tc=647 K and critical pressure Pc=22.1 MPa. This is most likely:
Answer: B
These are the critical constants for water. This falls within standard thermodynamic property tables for water.
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Q.26Easy
The enthalpy of vaporization (latent heat) of water at 100°C is 2257 kJ/kg. This represents:
Answer: C
Latent heat is absorbed during vaporization and released during condensation. Both statements are correct.
Q.27Easy
The relationship between specific heats Cp - Cv for an ideal gas is:
Answer: A
Mayer's relation: Cp - Cv = R (per mole). This is fundamental for ideal gases.
Q.28Easy
Which of the following statements about entropy is INCORRECT?
Answer: D
The Second Law states entropy of the universe INCREASES (ΔS_universe > 0) for spontaneous/irreversible processes, not decreases.
Q.29Easy
A heat engine operates between two thermal reservoirs at temperatures 600 K and 300 K. What is the maximum possible efficiency of this engine?
Answer: B
Maximum efficiency of a heat engine = 1 - (T_cold/T_hot) = 1 - (600300) = 0.50 or 50% (Carnot efficiency)
Q.30Easy
In a Diesel cycle, which process represents constant pressure heat addition?
Answer: B
The Diesel cycle has constant pressure heat addition (isobaric process) between the initial compression and subsequent expansion, distinguishing it from the Otto cycle
Q.31Easy
In a constant volume process (isochoric), if temperature increases from 300 K to 600 K, the pressure ratio P₂/P₁ will be:
Answer: C
For isochoric process: P/T = constant, so P₂/P₁ = T₂/T₁ = 300600 = 2.0
Q.32Easy
Which law states that the total energy of an isolated system remains constant?
Answer: B
The First Law of Thermodynamics is the conservation of energy principle for thermodynamic systems
Q.33Easy
Which process is represented when a gas is compressed without any heat transfer to or from surroundings?
Answer: C
An adiabatic process has no heat transfer (Q = 0) between the system and surroundings
Q.34Easy
For an ideal gas, if both pressure and volume are doubled, the temperature ratio T₂/T₁ will be:
Answer: C
Using ideal gas law PV = nRT: T₂/T₁ = (P₂V₂)/(P₁V₁) = (2P₁ × 2V₁)/(P₁V₁) = 4
Q.35Easy
In a closed system, 50 kJ of heat is added and 30 kJ of work is done by the system. The change in internal energy is:
Answer: A
From First Law: ΔU = Q - W = 50 - 30 = 20 kJ (taking work done by system as positive)
Q.36Easy
According to the Second Law of Thermodynamics, for a spontaneous process in an isolated system, the entropy must:
Answer: C
Second Law states that entropy of an isolated system increases for spontaneous (irreversible) processes and remains constant only for reversible processes