For the reaction 2H₂ + O₂ → 2H₂O, ΔH = -572 kJ/mol. How much heat is released when 4 moles of H₂ react?
Answer: C
Given reaction releases 572 kJ for 2 moles of H₂. For 4 moles of H₂, heat released = (2572) × 4 = 1144 kJ
Q.22Easy
The osmotic pressure of a solution at 27°C containing 0.1 mol of solute in 1 L is approximately:
Answer: A
π = nRT/V = (0.1 × 0.0821 × 300)/1 = 2.463 atm
Q.23Medium
Which colligative property depends on the nature of solute as well as its concentration?
Answer: A
Osmotic pressure depends on solute nature because it involves membrane interactions. Other colligative properties depend only on number of solute particles
Q.24Easy
For a first-order reaction with half-life of 69.3 minutes, the rate constant k is:
Answer: A
For first-order reaction: t₁/₂ = 0.693/k, so k = 0.69693.3 = 1.0 × 10⁻³ min⁻¹
Q.25Easy
In electrochemistry, the reduction potential of Cu²⁺/Cu is +0.34 V and Zn²⁺/Zn is -0.76 V at 25°C. What is E°cell for Zn-Cu cell?
An ideal gas undergoes isothermal compression from 10 L to 5 L at constant temperature. The work done ON the gas is:
Answer: A
In compression, volume decreases and work is done ON the gas, making w positive (in physics convention). W = -nRT ln(Vf/Vi) where Vf < Vi
Q.29Medium
The Born-Landé equation is used to calculate which property?
Answer: B
Born-Landé equation specifically calculates lattice energy of ionic compounds based on ionic radii and charges
Q.30Medium
For the reaction: PCl₅(g) ⇌ PCl₃(g) + Cl₂(g), if initial pressure of PCl₅ is 1 atm and degree of dissociation is 0.4, what is Kp at constant total pressure?