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A buffer solution is prepared by mixing 100 mL of 0.1 M acetic acid (CH₃COOH) and 100 mL of 0.1 M sodium acetate (CH₃COONa). Using Henderson-Hasselbalch equation, if Ka = 1.8 × 10⁻⁵, what is the pH?
Correct Answer:
B. 4.74
EXPLANATION
pH = pKa + log([A⁻]/[HA]). pKa = -log(1.8 × 10⁻⁵) ≈ 4.74. Since [A⁻] = [HA] (equal concentrations), log(1) = 0. Therefore, pH = 4.74.