Govt Exams
The Second Law states entropy of the universe INCREASES (ΔS_universe > 0) for spontaneous/irreversible processes, not decreases.
ηt = (h_in - h_out_actual)/(h_in - h_out_isentropic) → 0.85 = (2800 - h_actual)/(2800 - 2300) → h_actual = 2575 kJ/kg
van der Waals equation: (P + a/V²)(V - b) = RT. The 'a' term represents attractive forces; 'b' represents excluded volume.
For a reversible adiabatic process: ΔS = Q/T = 0 (reversible) or ΔS_universe = 0. Entropy of the system remains constant.
Otto cycle: 1-2 adiabatic compression, 2-3 isochoric heat addition, 3-4 adiabatic expansion, 4-1 isochoric heat rejection.
Mayer's relation: Cp - Cv = R (per mole). This is fundamental for ideal gases.
In throttling, the process is isenthalpic (h₁ = h₂). Temperature may change depending on the Joule-Thomson coefficient.
In adiabatic process, Q=0, so ΔU = -W or ΔU = W (depending on sign convention). Work done ON gas is positive, increasing internal energy.
W = [nRT₁/(n-1)][(P₂/P₁)^((n-1)/n) - 1] = [1.25×287×300/0.25][10^0.2 - 1] ≈ 220 kJ/kg
Latent heat is absorbed during vaporization and released during condensation. Both statements are correct.