A heat engine operating between two temperature reservoirs has a maximum theoretical efficiency given by:
Answer: A
The Carnot efficiency is the maximum theoretical efficiency for any heat engine, given by η = 1 - (T_C/T_H), where temperatures are in Kelvin.
Q.2Medium
In a throttling process (Joule-Thomson expansion), the enthalpy of the fluid:
Answer: C
Throttling is an isenthalpic process where enthalpy remains constant (H_initial = H_final) as the fluid expands through a restriction.
Q.3Medium
The availability or exergy of a system is zero when the system is in:
Answer: A
Exergy is maximum work available from a system. At dead state (T₀, P₀, same as surroundings), exergy is zero as no useful work can be extracted.
Q.4Medium
For a real gas, the compressibility factor Z is defined as:
Answer: A
Compressibility factor Z = PV/(nRT). For ideal gas, Z = 1. For real gases, Z ≠ 1 due to molecular interactions.
Q.5Medium
The polytropic process for an ideal gas follows PV^n = constant. When n = 0, the process is:
Answer: A
When n = 0, PV⁰ = P = constant, which is an isobaric process. When n = 1 (isothermal), n = γ (adiabatic), n = ∞ (isochoric).
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Q.6Medium
In a closed system, the total energy balance equation for a time interval is:
Answer: B
First Law: ΔE_system = Q - W, where Q is heat added to system and W is work done by system. This is the IUPAC convention.
Q.7Medium
Two bodies at different temperatures are brought into contact in an isolated system. The total entropy of the system will:
Answer: C
For an irreversible process in an isolated system, total entropy increases (ΔS_total > 0). Heat transfer between bodies at different temperatures is irreversible.
Q.8Medium
The specific heat capacity at constant volume (Cv) for a monatomic ideal gas is:
Answer: A
For a monatomic ideal gas with 3 translational degrees of freedom: Cv = (23)R. For diatomic: (25)R; for polyatomic: (27)R.
Q.9Medium
In a vapour compression refrigeration cycle, the throttling device (expansion valve) causes:
Answer: C
The throttling process is isenthalpic (constant enthalpy). The enthalpy remains the same before and after the expansion valve.
Q.10Medium
A piston-cylinder device contains 0.5 kg of steam at 200°C. Heat is removed and the steam condenses to saturated liquid at the same temperature. The latent heat of vaporization at 200°C is 1941 kJ/kg. Calculate heat removed.
Answer: A
Q = m × L_fg = 0.5 kg × 1941 kJ/kg = 970.5 kJ heat is removed during condensation
Q.11Medium
In the Rankine cycle, which process involves expansion in a turbine?
Answer: C
In an ideal Rankine cycle, turbine expansion is isentropic (reversible and adiabatic), maximizing work output. Real turbines follow this closely but with some irreversibilities.
Q.12Medium
Which of the following processes is impossible according to the second law of thermodynamics?
Answer: D
The second law states that entropy of an isolated system must increase or remain constant (reversible). A decrease in total entropy violates the second law and is impossible.
Q.13Medium
What is the dryness fraction (quality) of steam at a state where internal energy u = 2400 kJ/kg, u_f = 1317.3 kJ/kg, and u_fg = 1753.7 kJ/kg?
Answer: A
u = u_f + x × u_fg, so x = (u - u_f)/u_fg = (2400 - 1317.3)/1753.7 = 1082.17537.7 ≈ 0.62
Q.14Medium
In a polytropic process PV^n = constant, if n = 1, the process is:
Answer: B
For polytropic process with n=1: PV = constant, which is the ideal gas law at constant temperature, making it isothermal (T = constant).
Q.15Medium
In an Otto cycle, the compression ratio is 10 and γ = 1.4. Calculate the thermal efficiency.
At what condition is the specific heat capacity at constant pressure equal to infinity?
Answer: B
During phase transitions (like vaporization at constant T and P), infinite heat can be absorbed without temperature change, making C_p → ∞.
Q.17Medium
A heat engine receives 2000 J from a hot reservoir and rejects 1200 J to a cold reservoir. What is the thermal efficiency and work output?
Answer: A
Efficiency η = W/Q_in = (Q_in - Q_out)/Q_in = (2000-1200)/2000 = 2000800 = 0.4 = 40%. Work output W = 800 J
Q.18Medium
A reversible heat engine operates between two thermal reservoirs. If the temperature of the hot reservoir is 500 K and the cold reservoir is 300 K, what is the maximum possible efficiency of this engine?
Answer: A
Maximum efficiency occurs in a Carnot engine: η = 1 - (T_cold/T_hot) = 1 - (500300) = 1 - 0.6 = 0.4 or 40%
Q.19Medium
Which of the following statements is correct regarding the first law of thermodynamics?
Answer: C
The first law states that dU = Q - W, where heat (Q) and work (W) are energy transfer mechanisms, not state properties. Internal energy (U) is a state property.
Q.20Medium
During an adiabatic expansion of an ideal gas, the temperature of the gas decreases. This is because:
Answer: B
In adiabatic process, Q = 0. From first law: dU = -W. During expansion, W > 0, so dU < 0, meaning internal energy and temperature decrease.