Govt Exams
Faraday's first law states that the mass of substance deposited/dissolved during electrolysis is directly proportional to the quantity of electricity (charge) passed through the electrolyte.
In a galvanic cell, the anode is the negative electrode where oxidation occurs. The cathode is positive where reduction occurs.
Electrical conductivity is measured in Siemens per meter (S·m⁻¹). Ω·m is the unit of resistivity, which is the inverse of conductivity.
In electrolysis, oxidation occurs at the ANODE, not the cathode. The cathode is where reduction occurs. At the anode, electrons are removed from species.
The Nernst equation at 25°C is E = E° + (0.0592/n) log Q, where Q is the reaction quotient and n is the number of electrons transferred.
One mole of electrons carries a charge equal to Faraday's constant, which is approximately 96485 C/mol or 96500 C/mol.
In a galvanic cell, oxidation occurs at the anode. The anode is the negative electrode where electrons are released.
Electrical conductivity is measured in Siemens per meter (S·m⁻¹). Ω·m is the unit of resistivity, which is the reciprocal of conductivity.
At high temperatures in the blast furnace, carbon monoxide (CO) is the primary reducing agent that converts iron oxides to metallic iron. Although coke produces CO, the actual reduction occurs through CO: Fe₂O₃ + 3CO → 2Fe + 3CO₂. This is thermodynamically favorable at furnace temperatures.
MnO₂ is the standard catalyst for KClO₃ decomposition, significantly lowering the decomposition temperature from ~400°C to ~240°C. It acts as a heterogeneous catalyst.