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JEE Chemistry
Electrochemistry

Chemistry questions for JEE Main — Physical, Organic, Inorganic Chemistry.

29 Q 5 Topics Take Mock Test
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Difficulty: All Easy Medium Hard 21–29 of 29
Topics in JEE Chemistry
The Nernst equation is used to calculate:
A Cell potential under non-standard conditions
B Rate of reaction
C Activation energy
D Heat of reaction
Correct Answer:  A. Cell potential under non-standard conditions
EXPLANATION

The Nernst equation: E = E° - (RT/nF)ln(Q) calculates the cell potential when concentrations are not at standard state (1 M).

Test
What does Faraday's first law of electrolysis state?
A The amount of substance deposited is directly proportional to the charge passed
B The conductivity of solution decreases with dilution
C EMF is inversely proportional to current
D Reduction always occurs at the cathode
Correct Answer:  A. The amount of substance deposited is directly proportional to the charge passed
EXPLANATION

Faraday's first law states that the mass of substance deposited/dissolved during electrolysis is directly proportional to the quantity of electricity (charge) passed through the electrolyte.

Test
In a galvanic cell, which electrode acts as the negative terminal?
A Cathode
B Anode
C Salt bridge
D Both anode and cathode
Correct Answer:  B. Anode
EXPLANATION

In a galvanic cell, the anode is the negative electrode where oxidation occurs. The cathode is positive where reduction occurs.

Test
What is the SI unit of electrical conductivity?
A S·m⁻¹
B Ω·m
C S·cm
D Ω·cm⁻¹
Correct Answer:  A. S·m⁻¹
EXPLANATION

Electrical conductivity is measured in Siemens per meter (S·m⁻¹). Ω·m is the unit of resistivity, which is the inverse of conductivity.

Test
Which of the following statements about electrolysis is INCORRECT?
A Electrolysis is a non-spontaneous process
B In electrolysis, oxidation occurs at the cathode
C Electrical energy drives the electrolysis reaction
D The anode in electrolysis is positively charged
Correct Answer:  B. In electrolysis, oxidation occurs at the cathode
EXPLANATION

In electrolysis, oxidation occurs at the ANODE, not the cathode. The cathode is where reduction occurs. At the anode, electrons are removed from species.

Test
The Nernst equation relates cell potential to concentration. At 25°C, which form is correct?
A E = E° + (0.059/n) log Q
B E = E° - (0.0592/n) log Q
C E = E° + (0.0592/n) log Q
D E = E° - (0.059/n) log(1/Q)
Correct Answer:  C. E = E° + (0.0592/n) log Q
EXPLANATION

The Nernst equation at 25°C is E = E° + (0.0592/n) log Q, where Q is the reaction quotient and n is the number of electrons transferred.

Test
What is the charge on one mole of electrons?
A 1.6 × 10⁻¹⁹ C
B 6.022 × 10²³ C
C 96485 C
D 1.6 × 10⁻¹⁹ × 6.022 × 10²³ C
Correct Answer:  C. 96485 C
EXPLANATION

One mole of electrons carries a charge equal to Faraday's constant, which is approximately 96485 C/mol or 96500 C/mol.

Test
In a galvanic cell, which electrode acts as the anode?
A The electrode where reduction occurs
B The electrode where oxidation occurs
C The electrode connected to the positive terminal
D The electrode made of inert material
Correct Answer:  B. The electrode where oxidation occurs
EXPLANATION

In a galvanic cell, oxidation occurs at the anode. The anode is the negative electrode where electrons are released.

Test
Which of the following is the SI unit of electrical conductivity?
A S·m⁻¹
B Ω·m
C A·V⁻¹
D S·m²
Correct Answer:  A. S·m⁻¹
EXPLANATION

Electrical conductivity is measured in Siemens per meter (S·m⁻¹). Ω·m is the unit of resistivity, which is the reciprocal of conductivity.

Test
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