Govt. Exams
Entrance Exams
Gadolinium has atomic number 64 with configuration [Xe]4f⁷5d¹6s². The half-filled 4f⁷ configuration makes Gd exceptionally stable. This is the only lanthanide with a 5d electron, making it unique among the lanthanide series.
Permanganate ions (MnO₄⁻) oxidize ethanol to acetaldehyde and are themselves reduced to colorless Mn²⁺ ions (or MnO₂ depending on pH), causing the purple color to fade. This is a classic redox reaction where the oxidation state of Mn changes from +7 to +2.
Be (1s² 2s²) has a filled 2s orbital which is more stable. Additionally, smaller size means electrons are closer to nucleus. Both factors increase ionization potential.
MgO has the highest lattice energy due to smallest cation (Mg²⁺) and anion (O²⁻) sizes combined with higher charges. Order: MgO > NaCl > CaO > KCl.
PCl₃ has trigonal pyramidal geometry due to one lone pair on P. The bond angle is reduced from 120° (ideal trigonal) to 101.8° due to lone pair repulsion.
Be²⁺ has the smallest size and highest charge density, making it the strongest Lewis acid. It undergoes extensive hydrolysis. The order is Be²⁺ > Al³⁺ > Mg²⁺ > Ba²⁺.
Rapid mixing increases collision frequency. The presence of AgCl seed crystal provides nucleation sites. Both factors enhance precipitation rate by different mechanisms.
Pt²⁺ is d⁸ with strong field Cl⁻ ligands. The dsp² hybridization gives square planar geometry, which is the preferred geometry for d⁸ complexes with strong field ligands.
Both MnO₂ and Pt catalyze H₂O₂ decomposition to H₂O and O₂. MnO₂ is a heterogeneous catalyst while Pt can function as both heterogeneous and homogeneous catalyst.
SiCl₄ is most covalent due to small Si⁴⁺ size and high charge density. Covalent character increases: NaCl < MgCl₂ < AlCl₃ < SiCl₄.
