Govt. Exams
Entrance Exams
For isobaric process: dS = dQ/T = nCp dT/T. Integrating: ΔS = nCp ln(T2/T1) or specific entropy Δs = Cp ln(T2/T1)
Isentropic efficiency = Actual work output / Isentropic work output = 0.85. It compares real process with ideal isentropic process.
Throttling is an isenthalpic process (constant enthalpy). Temperature may change for real gases due to Joule-Thomson effect.
In adiabatic process, Q = 0. From first law: dU = -W. During expansion, W > 0, so dU < 0, meaning internal energy and temperature decrease.
The first law states that dU = Q - W, where heat (Q) and work (W) are energy transfer mechanisms, not state properties. Internal energy (U) is a state property.
Maximum efficiency occurs in a Carnot engine: η = 1 - (T_cold/T_hot) = 1 - (300/500) = 1 - 0.6 = 0.4 or 40%
Efficiency η = W/Q_in = (Q_in - Q_out)/Q_in = (2000-1200)/2000 = 800/2000 = 0.4 = 40%. Work output W = 800 J
During phase transitions (like vaporization at constant T and P), infinite heat can be absorbed without temperature change, making C_p → ∞.
Otto cycle efficiency = 1 - (1/r^(γ-1)) = 1 - (1/10^0.4) = 1 - (1/2.512) = 1 - 0.3981 = 0.602 ≈ 60.2%
For polytropic process with n=1: PV = constant, which is the ideal gas law at constant temperature, making it isothermal (T = constant).