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Chemical Engineering
Chemical Reaction Engineering

Process design, thermodynamics, reactions

23 Q 5 Topics Take Mock Test
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Difficulty: All Easy Medium Hard 1–10 of 23
Topics in Chemical Engineering
In CSTR, if inlet concentration C_A0 = 2 M, outlet concentration C_A = 0.5 M, what is fractional conversion?
A 0.25
B 0.5
C 0.75
D 1.0
Correct Answer:  C. 0.75
EXPLANATION

Conversion X = (C_A0 - C_A)/C_A0 = (2 - 0.5)/2 = 0.75 or 75%.

Test
What is the space-time (τ) in a PFR if reactor volume is 100 L and volumetric feed rate is 10 L/min?
A 0.1 min
B 1 min
C 10 min
D 100 min
Correct Answer:  C. 10 min
EXPLANATION

Space-time τ = V/v₀ = 100/10 = 10 min.

Test
Which of the following statements about adiabatic reactors is correct?
A Temperature remains constant throughout
B Heat exchange with surroundings occurs freely
C Temperature changes according to heat of reaction
D No chemical reaction occurs
Correct Answer:  C. Temperature changes according to heat of reaction
EXPLANATION

In adiabatic reactors, Q = 0, so ΔT depends on heat of reaction (ΔH_r) and heat capacity of reactants.

Test
For a reversible reaction at equilibrium, which statement is true?
A Forward reaction rate = zero
B Forward reaction rate = Reverse reaction rate
C Reverse reaction rate = zero
D Both rates are maximum
Correct Answer:  B. Forward reaction rate = Reverse reaction rate
EXPLANATION

At equilibrium, the net rate is zero because forward and reverse reaction rates are equal.

Test
For the reaction A + B → C, the rate law is r = kC_A²C_B. What is the overall order of reaction?
A First order
B Second order
C Third order
D Cannot be determined
Correct Answer:  C. Third order
EXPLANATION

Overall order = sum of individual orders = 2 + 1 = 3.

Test
What is the order of reaction if the half-life period is independent of initial concentration?
A Zero order
B First order
C Second order
D Third order
Correct Answer:  B. First order
EXPLANATION

For first-order reactions, t₁/₂ = 0.693/k, which is independent of initial concentration C₀.

Test
For the reaction 2A + B → Products, if the reaction is 2nd order in A and 1st order in B, the rate equation is:
A r = k[A]²[B]
B r = k[A][B]²
C r = k([A]² + [B])
D r = k[A]³[B]
Correct Answer:  A. r = k[A]²[B]
EXPLANATION

Reaction order is determined by experimental data, not stoichiometry. The given orders are 2nd in A and 1st in B, so rate law is r = k[A]²[B].

Test
The conversion in a batch reactor at any time can be found by integrating the rate equation. For a first-order reaction, the half-life is:
A Independent of initial concentration
B Proportional to initial concentration
C Inversely proportional to the rate constant
D Both A and C are correct
Correct Answer:  D. Both A and C are correct
EXPLANATION

For first-order: t₁/₂ = ln(2)/k = 0.693/k, which is independent of C₀ and inversely proportional to k.

Test
The Damköhler number (Da) for a chemical reaction is defined as the ratio of:
A Reaction time to residence time
B Residence time to reaction time
C Conversion to equilibrium conversion
D Rate constant to flow velocity
Correct Answer:  B. Residence time to reaction time
EXPLANATION

Da = (residence time)/(characteristic reaction time) = kτC^(n-1). When Da >> 1, reaction is fast; Da << 1, reaction is slow.

Test
Which of the following statements about residence time distribution (RTD) is correct?
A RTD is independent of reactor geometry and flow conditions
B RTD describes the fraction of fluid elements spending time between t and t+dt in the reactor
C RTD is only applicable to laminar flow reactors
D RTD cannot be experimentally determined using tracer studies
Correct Answer:  B. RTD describes the fraction of fluid elements spending time between t and t+dt in the reactor
EXPLANATION

RTD characterizes how long different fluid elements spend in a reactor and is fundamental to reactor design, independent of whether flow is laminar or turbulent.

Test
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