Govt. Exams
Entrance Exams
Shrinking core model applies: external diffusion, ash diffusion, and chemical reaction all contribute. Modern focus on clean energy requires optimized design.
Due to higher solute rejection, solutes accumulate near membrane surface, increasing local osmotic pressure and reducing driving force.
Φ = L√(k/D). When Φ >> 1, diffusion controls; when Φ << 1, kinetics controls. Critical for reactor design optimization.
η = (actual reaction rate)/(rate if all surface at bulk concentration). Important in catalytic reactors where diffusion and reaction compete.
Colburn analogy: j_D = (Sh)/(Re·Sc^(1/3)) ≈ j_H ≈ f/2 for smooth surfaces. Useful for correlating data when only one phenomenon is studied.
For ion exchange, intraparticle diffusion through pores is the rate-limiting step. External film resistance is negligible in comparison.
When one component condenses/reacts, equal molar counter-diffusion assumption breaks down. Stefan factor (B_m) corrects for net molar flow.
For gas-liquid systems, 1/K_OL = 1/k_L + 1/(m*k_G), where m is the distribution coefficient. This accounts for both liquid and gas side resistances.
The Chilton-Colburn analogy states that j_D = j_H = f_D/2, assuming equivalent Pr and Sc values, relating mass transfer to friction factor.
According to Chapman-Enskog theory, D_AB ∝ T^(3/2)/P for gases. Thus, D_AB is inversely proportional to pressure at constant temperature.