Govt. Exams
Entrance Exams
The Kremser equation requires initial and final solute concentrations or minimum separation requirements, which are not provided in the question.
The molar flux equation in terms of mole fractions is N_A = cD_AB(dy_A/dz) + y_A(N_A + N_B), accounting for bulk flow effects.
From Chapman-Enskog theory, D_AB ∝ T^(3/2)/(P × σ²) × √(M_total), where D_AB is inversely related to molecular mass through the collision cross-section dependency.
k_L·a in bioreactors depends on fluid mechanics (impeller speed, gas flow rate), liquid properties affecting k_L, and equipment design affecting interfacial area 'a'. Temperature indirectly affects through viscosity changes.
When Le = 1 (Sc/Pr = 1), both analogy relationships hold: α = D_AB and h/ρc_p = k_L, making heat and mass transfer coefficients proportionally equal.
For smooth pipes in turbulent flow, j_D ≈ 0.023 Re^(-0.2), which is analogous to the Dittus-Boelert correlation for heat transfer with the Colburn j-factor approach.
A small Henry's law constant (H) for NH₃ indicates high solubility in the liquid phase. Since 1/K_L = 1/k_L + H/k_G, a small H means the gas phase resistance dominates.