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Difficulty: All Easy Medium Hard 111–117 of 117
Topics in Chemical Engineering
Q.111 Hard Mass Transfer
For a countercurrent liquid-liquid extraction process, the Kremser equation is used. What is the minimum number of stages required if the separation factor is 2.0 and the extraction factor is 1.5?
A Less than 3 stages
B Approximately 3-4 stages
C Approximately 5-6 stages
D Cannot be determined without additional information
Correct Answer:  D. Cannot be determined without additional information
EXPLANATION

The Kremser equation requires initial and final solute concentrations or minimum separation requirements, which are not provided in the question.

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Q.112 Hard Mass Transfer
For a binary diffusion process, the flux equation according to Fick's law in terms of mole fractions is given by:
A N_A = -cD_AB(dc_A/dz) + y_A(N_A + N_B)
B N_A = cD_AB(dy_A/dz) + y_A(N_A + N_B)
C N_A = D_AB(dρ_A/dz)
D N_A = -D_AB(d²c_A/dz²)
Correct Answer:  B. N_A = cD_AB(dy_A/dz) + y_A(N_A + N_B)
EXPLANATION

The molar flux equation in terms of mole fractions is N_A = cD_AB(dy_A/dz) + y_A(N_A + N_B), accounting for bulk flow effects.

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Q.113 Hard Mass Transfer
Which statement about the relationship between diffusivity and molar mass is correct according to kinetic theory?
A D_AB ∝ √(T/M_total)
B D_AB is independent of molar mass
C D_AB ∝ (M_A × M_B)^(1/2)
D D_AB is inversely proportional to molecular weight
Correct Answer:  A. D_AB ∝ √(T/M_total)
EXPLANATION

From Chapman-Enskog theory, D_AB ∝ T^(3/2)/(P × σ²) × √(M_total), where D_AB is inversely related to molecular mass through the collision cross-section dependency.

Test
Q.114 Hard Mass Transfer
A bioprocess company needs to calculate oxygen transfer rate in an aerated bioreactor. The volumetric mass transfer coefficient k_L·a depends on which parameters?
A Superficial gas velocity and interfacial area per unit volume only
B Liquid properties (viscosity, surface tension), aeration rate, and impeller design
C Temperature and pressure only
D Oxygen partial pressure in inlet gas
Correct Answer:  B. Liquid properties (viscosity, surface tension), aeration rate, and impeller design
EXPLANATION

k_L·a in bioreactors depends on fluid mechanics (impeller speed, gas flow rate), liquid properties affecting k_L, and equipment design affecting interfacial area 'a'. Temperature indirectly affects through viscosity changes.

Test
Q.115 Hard Mass Transfer
For simultaneous heat and mass transfer in a wet bulb thermometer, the Lewis number (Le) is defined as Le = Sc/Pr. If Le = 1, what can be inferred?
A Heat and mass transfer coefficients are equal
B Thermal diffusivity equals mass diffusivity
C Both a and b are correct
D The system is at equilibrium
Correct Answer:  C. Both a and b are correct
EXPLANATION

When Le = 1 (Sc/Pr = 1), both analogy relationships hold: α = D_AB and h/ρc_p = k_L, making heat and mass transfer coefficients proportionally equal.

Test
Q.116 Hard Mass Transfer
For turbulent flow in a pipe, the Colburn analogy for mass transfer is: j_D = (Sh)/(Re × Sc^(1/3)). Which correlation best estimates j_D for smooth pipes?
A j_D = 0.023 Re^(-0.2)
B j_D = 0.023 Re^(0.2)
C j_D = 0.037 Re^(-0.2)
D j_D = f/2 (where f is Fanning friction factor)
Correct Answer:  A. j_D = 0.023 Re^(-0.2)
EXPLANATION

For smooth pipes in turbulent flow, j_D ≈ 0.023 Re^(-0.2), which is analogous to the Dittus-Boelert correlation for heat transfer with the Colburn j-factor approach.

Test
Q.117 Hard Mass Transfer
A pharmaceutical company is designing an absorption tower for NH₃ removal from air using H₂SO₄ solution. The Henry's law constant for NH₃ at 25°C is very small. What does this indicate about the system?
A Gas phase controls the mass transfer
B Liquid phase controls the mass transfer
C Both phases equally resist mass transfer
D Equilibrium conversion is very low
Correct Answer:  A. Gas phase controls the mass transfer
EXPLANATION

A small Henry's law constant (H) for NH₃ indicates high solubility in the liquid phase. Since 1/K_L = 1/k_L + H/k_G, a small H means the gas phase resistance dominates.

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