Govt. Exams
Entrance Exams
COP_heating = T_H/(T_H - T_C) = 330/(330-270) = 330/60 = 5.5. Q_H = W × COP = 1000 × 5.5 = 5500 J. Adding work input: Total = 5500 + 500 = 6000 J
T_2/T_1 = (P_2/P_1)^((γ-1)/γ) = 8^(0.4/1.4) = 8^0.2857 ≈ 1.734. T_2 = 300 × 1.734 ≈ 520.2 K
Diesel cycle efficiency = 1 - (1/r^(γ-1)) × [(r_c^γ - 1)/(γ(r_c - 1))] where r_c = cutoff ratio. With r=16, r_c=1.5, γ=1.4, efficiency ≈ 63.5%
Otto cycle efficiency: η = 1 - 1/r^(γ-1) = 1 - 1/9^0.4 = 1 - 1/2.28 ≈ 0.558 or 55.8% ≈ 58%.
Maxwell relations come from the Schwarz theorem applied to thermodynamic potentials (U, H, F, G). For example, from dG = -SdT + VdP: (∂S/∂P)_T = -(∂V/∂T)_P.
For Brayton cycle: η = 1 - 1/r_p^((γ-1)/γ). As pressure ratio r_p increases, efficiency increases. This is why modern turbojets use high pressure ratios.
For a reversible process: ΔS_universe = ΔS_system + ΔS_surroundings = 0. The system's entropy can increase or decrease, but total entropy doesn't change.
Clausius-Clapeyron: dp/dT = L/(T·Δv), where L is latent heat of vaporization and relates pressure-temperature relationship at phase equilibrium.
For Carnot refrigerator: COP_ref = T_C/(T_H - T_C) = 250/(300-250) = 250/50 = 5.