Govt. Exams
Entrance Exams
Second Law states that entropy of an isolated system increases for spontaneous (irreversible) processes and remains constant only for reversible processes
From First Law: ΔU = Q - W = 50 - 30 = 20 kJ (taking work done by system as positive)
Using ideal gas law PV = nRT: T₂/T₁ = (P₂V₂)/(P₁V₁) = (2P₁ × 2V₁)/(P₁V₁) = 4
An adiabatic process has no heat transfer (Q = 0) between the system and surroundings
The First Law of Thermodynamics is the conservation of energy principle for thermodynamic systems
For isochoric process: P/T = constant, so P₂/P₁ = T₂/T₁ = 600/300 = 2.0
The Diesel cycle has constant pressure heat addition (isobaric process) between the initial compression and subsequent expansion, distinguishing it from the Otto cycle
Maximum efficiency of a heat engine = 1 - (T_cold/T_hot) = 1 - (300/600) = 0.50 or 50% (Carnot efficiency)
The Second Law states entropy of the universe INCREASES (ΔS_universe > 0) for spontaneous/irreversible processes, not decreases.
Mayer's relation: Cp - Cv = R (per mole). This is fundamental for ideal gases.