Govt. Exams
Entrance Exams
For any cycle: ΔU_cycle = 0. First law: Q_net = W_net confirms energy conservation. 150 = 150 ✓
Using Mayer's relation: Cp - Cv = R. Therefore, Cp = 5R/2 + R = 7R/2
Entropy is defined as dS = dQ_rev/T. Units: Joules/Kelvin = J/K. This is the fundamental SI unit for entropy.
In constant volume process: W = ∫PdV = 0. From first law: ΔU = Q - W = -300 - 0 = -300 J
Water has exceptionally high specific heat (~4.18 kJ/kg·K), much higher than metals (iron ~0.46) and air (~1.01). This is due to hydrogen bonding in water.
From first law: ΔU = Q - W = 500 - 200 = 300 J. Internal energy increases by 300 J.
Heat (Q) and work (W) are path-dependent quantities, not state functions. Internal energy, enthalpy, and entropy are state functions depending only on initial and final states.
A reversible adiabatic process has constant entropy (dS = 0), making it isentropic. This is a key assumption in many thermodynamic analysis for ideal processes.
The Mayer relation: C_p - C_v = R, where R is the specific gas constant. This relation holds for all ideal gases.
The correct form is dU = δQ - δW, where δW = PdV for expansion work. This represents energy conservation in thermodynamic systems.