Govt. Exams
Entrance Exams
When n = 0, PV⁰ = P = constant, which is an isobaric process. When n = 1 (isothermal), n = γ (adiabatic), n = ∞ (isochoric).
Compressibility factor Z = PV/(nRT). For ideal gas, Z = 1. For real gases, Z ≠ 1 due to molecular interactions.
Exergy is maximum work available from a system. At dead state (T₀, P₀, same as surroundings), exergy is zero as no useful work can be extracted.
Throttling is an isenthalpic process where enthalpy remains constant (H_initial = H_final) as the fluid expands through a restriction.
The Carnot efficiency is the maximum theoretical efficiency for any heat engine, given by η = 1 - (T_C/T_H), where temperatures are in Kelvin.