Govt. Exams
Entrance Exams
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Topics in Chemical Engineering
In desorption-limited catalytic reactions, which step determines the overall reaction rate?
Correct Answer:
C. Product desorption from catalyst surface
EXPLANATION
When desorption is the rate-limiting step, products stick to the catalyst and their slow removal prevents further reaction cycles, controlling overall rate
For consecutive reactions A→B→C, the concentration of intermediate B is maximum at time t_max. This time depends on:
Correct Answer:
A. Only k₁ and k₂
EXPLANATION
t_max = ln(k₂/k₁)/(k₂-k₁), depends only on rate constants, independent of [A]₀
Which approximation is used in steady-state kinetics for enzyme reactions?
Correct Answer:
D. Both B and C
EXPLANATION
Both steady-state (d[ES]/dt = 0) and pre-equilibrium approximations are used in Michaelis-Menten derivation
For a reaction with E_a = 50 kJ/mol, if temperature is increased from 300K to 400K, by what factor does rate constant increase? (R = 8.314 J/mol·K)
Correct Answer:
C. 15.8 times
EXPLANATION
ln(k₂/k₁) = (50000/8.314)[1/300 - 1/400] = 2.76; k₂/k₁ = e^2.76 ≈ 15.8
Which reactor configuration gives maximum yield for a series reaction A→B→C where k₁ >> k₂?
Correct Answer:
A. Batch reactor with optimized residence time
EXPLANATION
For A→B→C series, batch allows control of residence time to maximize intermediate B before it converts to C
What is the activation energy for a reaction if its rate constant doubles when temperature increases from 300K to 310K?
Correct Answer:
B. 52.8 kJ/mol
EXPLANATION
Using Arrhenius equation: ln(k₂/k₁) = (Eₐ/R)[1/T₁ - 1/T₂]; ln(2) = (Eₐ/8.314)[1/300 - 1/310]; Eₐ ≈ 52.8 kJ/mol