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Chemical Engineering
Chemical Reaction Engineering

Process design, thermodynamics, reactions

26 Q 5 Topics Take Mock Test
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Difficulty: All Easy Medium Hard 21–26 of 26
Topics in Chemical Engineering
In desorption-limited catalytic reactions, which step determines the overall reaction rate?
A Reactant adsorption on catalyst surface
B Surface reaction between adsorbed species
C Product desorption from catalyst surface
D Diffusion of reactant to catalyst surface
Correct Answer:  C. Product desorption from catalyst surface
EXPLANATION

When desorption is the rate-limiting step, products stick to the catalyst and their slow removal prevents further reaction cycles, controlling overall rate

Test
For consecutive reactions A→B→C, the concentration of intermediate B is maximum at time t_max. This time depends on:
A Only k₁ and k₂
B Only initial concentration of A
C Both k₁, k₂ and initial concentration of A
D Temperature only
Correct Answer:  A. Only k₁ and k₂
EXPLANATION

t_max = ln(k₂/k₁)/(k₂-k₁), depends only on rate constants, independent of [A]₀

Test
Which approximation is used in steady-state kinetics for enzyme reactions?
A Quasi-equilibrium approximation
B Steady-state approximation for ES complex
C Pre-equilibrium approximation
D Both B and C
Correct Answer:  D. Both B and C
EXPLANATION

Both steady-state (d[ES]/dt = 0) and pre-equilibrium approximations are used in Michaelis-Menten derivation

Test
For a reaction with E_a = 50 kJ/mol, if temperature is increased from 300K to 400K, by what factor does rate constant increase? (R = 8.314 J/mol·K)
A 3.2 times
B 8.5 times
C 15.8 times
D 22.3 times
Correct Answer:  C. 15.8 times
EXPLANATION

ln(k₂/k₁) = (50000/8.314)[1/300 - 1/400] = 2.76; k₂/k₁ = e^2.76 ≈ 15.8

Test
Which reactor configuration gives maximum yield for a series reaction A→B→C where k₁ >> k₂?
A Batch reactor with optimized residence time
B CSTR operating at high temperature
C PFR with very high conversion
D Recycle reactor
Correct Answer:  A. Batch reactor with optimized residence time
EXPLANATION

For A→B→C series, batch allows control of residence time to maximize intermediate B before it converts to C

Test
What is the activation energy for a reaction if its rate constant doubles when temperature increases from 300K to 310K?
A 45.6 kJ/mol
B 52.8 kJ/mol
C 60.2 kJ/mol
D 72.5 kJ/mol
Correct Answer:  B. 52.8 kJ/mol
EXPLANATION

Using Arrhenius equation: ln(k₂/k₁) = (Eₐ/R)[1/T₁ - 1/T₂]; ln(2) = (Eₐ/8.314)[1/300 - 1/310]; Eₐ ≈ 52.8 kJ/mol

Test
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