Govt. Exams
Entrance Exams
According to the second law, entropy of an isolated system always increases for irreversible processes.
For spontaneous reactions, ΔG must be negative (ΔG < 0). This is the criterion for spontaneity at constant T and P.
First law: ΔU = Q - W = 1000 - 400 = 600 J
For isochoric process: P₁/T₁ = P₂/T₂, so T₂/T₁ = P₂/P₁ = 2
Q = mL = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J
For any ideal gas, Cp - Cv = R, regardless of molecular structure. This is derived from thermodynamic relations.
Maximum efficiency = 1 - (T₂/T₁) = 1 - (300/400) = 1 - 0.75 = 0.25 = 25%
In an isothermal process, ΔU = 0. By first law: Q = ΔU + W, therefore Q = W for an ideal gas.
Third law of thermodynamics: The entropy of a perfect crystal at absolute zero is zero. S(0K) = 0 for perfect crystals.
In any cyclic process, system returns to initial state. Since U is a state function, ΔU = 0 for complete cycles.