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According to the second law, entropy of an isolated system always increases for irreversible processes.
For spontaneous reactions, ΔG must be negative (ΔG < 0). This is the criterion for spontaneity at constant T and P.
First law: ΔU = Q - W = 1000 - 400 = 600 J
For isochoric process: P₁/T₁ = P₂/T₂, so T₂/T₁ = P₂/P₁ = 2
Q = mL = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J
For any ideal gas, Cp - Cv = R, regardless of molecular structure. This is derived from thermodynamic relations.
Maximum efficiency = 1 - (T₂/T₁) = 1 - (300/400) = 1 - 0.75 = 0.25 = 25%
In an isothermal process, ΔU = 0. By first law: Q = ΔU + W, therefore Q = W for an ideal gas.
Third law of thermodynamics: The entropy of a perfect crystal at absolute zero is zero. S(0K) = 0 for perfect crystals.
In any cyclic process, system returns to initial state. Since U is a state function, ΔU = 0 for complete cycles.
About NEET Physics Practice on iGET
NEET UG (National Eligibility cum Entrance Test) is the single national entrance exam for MBBS, BDS, AYUSH, and other undergraduate medical courses in India. Physics carries 180 marks (45 questions × 4 marks) out of the total 720 — making it a critical scoring section, especially for cracking AIIMS/JIPMER cutoffs.
iGET's NEET Physics practice covers all major chapters: Mechanics (Kinematics, Newton's Laws, Work-Energy-Power, Rotational Motion), Thermodynamics, Waves & Sound, Optics (Ray + Wave), Electricity (Current, Capacitance), Magnetism, Electromagnetic Induction, and Modern Physics (Atoms, Nuclei, Photoelectric Effect, Semiconductors).
Why iGET for NEET Physics
NCERT-aligned questions (NEET source), conceptual + numerical mix, detailed step-by-step solutions for every problem, formula sheets per chapter, previous year question patterns, and difficulty-graded practice (Easy/Medium/Hard) to help you progress systematically.
Smart preparation tip
Physics is the trickiest section in NEET — most aspirants score lowest here. Master Mechanics first (highest weightage), then Modern Physics (easiest scoring), then Electricity & Magnetism. Solve 30+ MCQs daily with a timer; aim for 80%+ accuracy before moving to the next chapter.