Govt. Exams
Entrance Exams
Permeance has units of mol/(m²·s·Pa) when flux is in mol/(m²·s) and driving force (pressure difference) is in Pa. It represents the ease of species permeation through the membrane.
Penetration theory (Higbie) assumes that fluid elements reach the interface, remain for a contact time θ, and then leave, with transient diffusion occurring during exposure.
A larger gap between the operating line and equilibrium line indicates greater concentration difference, which increases the driving force (ΔC) for mass transfer, leading to higher transfer rates.
For laminar flow over a flat plate, the Chilton-Colburn analogy gives Sh = 0.664 Re^0.5 Sc^(1/3), analogous to the Nusselt number in heat transfer.
For gas absorption with equilibrium relation y = Hx, the overall liquid phase coefficient is 1/K_L = 1/k_L + H/k_G, where H is Henry's law constant.
All three equations represent valid forms of mass transfer rate equations. Option A uses liquid phase coefficient, Option B is Fick's law, Option C uses gas phase coefficient, and all are interconnected through film theory.
In laminar flow, k ∝ D^(1/2). Therefore, if D doubles, k increases by √2 times (approximately 1.414 times).