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JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Q.1 Hard Thermodynamics
A gas sample undergoes a process where pressure decreases linearly with volume: P = P₀ - kV, where k is a constant. For 1 mole of ideal gas at constant temperature, what is the work done when volume changes from V₁ to V₂?
A P₀(V₂ - V₁) - k(V₂² - V₁²)/2
B ∫P dV = RT ln(V₂/V₁)
C P₀V₂ - P₀V₁
D k(V₂ - V₁)
Correct Answer:  A. P₀(V₂ - V₁) - k(V₂² - V₁²)/2
EXPLANATION

Work done: W = ∫P dV = ∫(P₀ - kV) dV from V₁ to V₂ = [P₀V - kV²/2] from V₁ to V₂ = P₀(V₂ - V₁) - k(V₂² - V₁²)/2

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Q.2 Hard Thermodynamics
A 2 kg mass of ice at 0°C is mixed with 5 kg of water at 80°C in a thermally insulated container. If latent heat of fusion = 3.36 × 10⁵ J/kg and specific heat of water = 4200 J/kg·K, determine the final state of the system.
A All ice melts; final temperature ≈ 46°C
B Some ice remains; final temperature = 0°C
C All ice melts; final temperature ≈ 32°C
D All water freezes; final temperature < 0°C
Correct Answer:  A. All ice melts; final temperature ≈ 46°C
EXPLANATION

Heat available from water cooling from 80°C to 0°C: Q = 5 × 4200 × 80 = 1.68 × 10⁶ J. Heat needed to melt ice: Q = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J. Since 1.68 × 10⁶ > 6.72 × 10⁵, all ice melts. Remaining heat: 1.68 × 10⁶ - 6.72 × 10⁵ = 1.008 × 10⁶ J raises temperature of 7 kg water: ΔT = 1.008 × 10⁶/(7 × 4200) ≈ 34.3°C → final temp ≈ 34°C

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Q.3 Hard Thermodynamics
Which thermodynamic process results in maximum work extraction from an ideal gas expanding from the same initial to final states?
A Isobaric process
B Isothermal process
C Isochoric process
D Adiabatic process
Correct Answer:  B. Isothermal process
EXPLANATION

For expansion between the same P-V states, isothermal process produces maximum work because W = nRT ln(V_f/V_i) is maximum when temperature is highest throughout the process.

Test
Q.4 Hard Thermodynamics
A gas sample at 300 K has an entropy of 200 J/K. When heated at constant pressure to 600 K, its entropy becomes:
A 200 + R ln(2) J/K
B 200 + nC_p ln(2) J/K
C 200 ln(2) J/K
D 400 J/K
Correct Answer:  B. 200 + nC_p ln(2) J/K
EXPLANATION

At constant pressure: ΔS = nC_p ln(T_f/T_i) = nC_p ln(600/300) = nC_p ln(2). Final entropy = 200 + nC_p ln(2) J/K

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Q.5 Hard Thermodynamics
For an ideal gas undergoing a polytropic process (PV^n = constant), the heat capacity is C = C_v + R/(1-n). For which value of n does the polytropic process become adiabatic?
A n = 1
B n = γ
C n = 0
D n = ∞
Correct Answer:  B. n = γ
EXPLANATION

For adiabatic process, Q = 0, so C = 0. This occurs when 1-n approaches infinity, which happens when n = γ. At n = γ, PV^γ = constant (adiabatic relation).

Test
Q.6 Hard Thermodynamics
A monatomic ideal gas undergoes a cyclic process ABCA where: A→B is isothermal expansion, B→C is isochoric process, C→A is adiabatic compression. If at point A, P = 1 atm, V = 1 L, and T = 300 K, and the volume doubles from A to B, find the heat absorbed during the isothermal process.
A 150 ln(2) J
B 300 ln(2) J
C 600 ln(2) J
D 900 ln(2) J
Correct Answer:  C. 600 ln(2) J
EXPLANATION

For isothermal process of ideal gas: Q = nRT ln(V_f/V_i) = W. n = PV/RT = (101325 × 0.001)/(8.314 × 300) ≈ 0.0405 mol. Q = nRT ln(2) = 0.0405 × 8.314 × 300 × ln(2) ≈ 600 ln(2) J

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Q.7 Hard Thermodynamics
In a free expansion of ideal gas into vacuum, the entropy change of system is:
A Zero
B Positive
C Negative
D Depends on initial temperature
Correct Answer:  B. Positive
EXPLANATION

Free expansion is irreversible with ΔU = 0 and W = 0, so Q = 0. Volume increases, so S = nR ln(V_f/V_i) > 0

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Q.8 Hard Thermodynamics
A reversible process has entropy change ΔS_sys = -100 J/K. The entropy change of universe is:
A Negative
B Positive
C Zero
D Cannot be determined
Correct Answer:  C. Zero
EXPLANATION

For reversible process: ΔS_universe = ΔS_sys + ΔS_surr = 0. Since ΔS_sys = -100, ΔS_surr = +100, making total change zero

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Q.9 Hard Thermodynamics
For a van der Waals gas, the critical point is characterized by:
A dP/dV = 0 and d²P/dV² = 0
B dP/dV > 0
C Temperature at which gas liquefies
D Point where all intermolecular forces vanish
Correct Answer:  A. dP/dV = 0 and d²P/dV² = 0
EXPLANATION

At critical point, both first and second derivatives of pressure with respect to volume are zero, marking the boundary of liquid-gas phase transition

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Q.10 Hard Thermodynamics
A heat engine operates between 600 K and 300 K reservoirs. It absorbs 5000 J from hot reservoir. For a Carnot engine operating between same temperatures, maximum work output would be:
A 2000 J
B 2500 J
C 3000 J
D 3500 J
Correct Answer:  B. 2500 J
EXPLANATION

Carnot efficiency = 1 - 300/600 = 0.5; W_max = η × Q_h = 0.5 × 5000 = 2500 J

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