Govt. Exams
Entrance Exams
Work done: W = ∫P dV = ∫(P₀ - kV) dV from V₁ to V₂ = [P₀V - kV²/2] from V₁ to V₂ = P₀(V₂ - V₁) - k(V₂² - V₁²)/2
Heat available from water cooling from 80°C to 0°C: Q = 5 × 4200 × 80 = 1.68 × 10⁶ J. Heat needed to melt ice: Q = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J. Since 1.68 × 10⁶ > 6.72 × 10⁵, all ice melts. Remaining heat: 1.68 × 10⁶ - 6.72 × 10⁵ = 1.008 × 10⁶ J raises temperature of 7 kg water: ΔT = 1.008 × 10⁶/(7 × 4200) ≈ 34.3°C → final temp ≈ 34°C
Theoretical maximum COP = T_cold/(T_hot - T_cold) = 250/(350-250) = 250/100 = 2.5
For adiabatic process: TV^(γ-1) = constant. T₁V₁^0.4 = T₂(1.5V₁)^0.4. T₂/T₁ = (1/1.5)^0.4 = 0.73^0.4 ≈ 0.73
At equilibrium: T_f = (400 + 300)/2 = 350 K. ΔS_A = m·c·ln(T_f/T_A) = 1×400×ln(350/400) = -56 J/K. ΔS_B = 1×400×ln(350/300) = 56.4 J/K. ΔS_total ≈ 11.2 J/K
Internal energy is a state function, so for a cyclic process where the system returns to its initial state, ΔU = 0 always, regardless of the path.
For isothermal process: W = nRT ln(V_f/V_i) = P₁V₁ ln(3V₁/V₁) = P₁V₁ ln(3)
For constant pressure: Q = n·Cp·ΔT. For diatomic gas, Cp = (7/2)R. Q = 3 × (7/2) × 8.314 × (600-300) = 3 × 3.5 × 8.314 × 300 = 26,194 × 2.85 ≈ 74,826 J
Maximum efficiency (Carnot efficiency) = 1 - (T_cold/T_hot) = 1 - (300/500) = 1 - 0.6 = 0.4 = 40%
For expansion between the same P-V states, isothermal process produces maximum work because W = nRT ln(V_f/V_i) is maximum when temperature is highest throughout the process.