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JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Q.1 Hard Thermodynamics
A gas sample undergoes a process where pressure decreases linearly with volume: P = P₀ - kV, where k is a constant. For 1 mole of ideal gas at constant temperature, what is the work done when volume changes from V₁ to V₂?
A P₀(V₂ - V₁) - k(V₂² - V₁²)/2
B ∫P dV = RT ln(V₂/V₁)
C P₀V₂ - P₀V₁
D k(V₂ - V₁)
Correct Answer:  A. P₀(V₂ - V₁) - k(V₂² - V₁²)/2
EXPLANATION

Work done: W = ∫P dV = ∫(P₀ - kV) dV from V₁ to V₂ = [P₀V - kV²/2] from V₁ to V₂ = P₀(V₂ - V₁) - k(V₂² - V₁²)/2

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Q.2 Hard Thermodynamics
A 2 kg mass of ice at 0°C is mixed with 5 kg of water at 80°C in a thermally insulated container. If latent heat of fusion = 3.36 × 10⁵ J/kg and specific heat of water = 4200 J/kg·K, determine the final state of the system.
A All ice melts; final temperature ≈ 46°C
B Some ice remains; final temperature = 0°C
C All ice melts; final temperature ≈ 32°C
D All water freezes; final temperature < 0°C
Correct Answer:  A. All ice melts; final temperature ≈ 46°C
EXPLANATION

Heat available from water cooling from 80°C to 0°C: Q = 5 × 4200 × 80 = 1.68 × 10⁶ J. Heat needed to melt ice: Q = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J. Since 1.68 × 10⁶ > 6.72 × 10⁵, all ice melts. Remaining heat: 1.68 × 10⁶ - 6.72 × 10⁵ = 1.008 × 10⁶ J raises temperature of 7 kg water: ΔT = 1.008 × 10⁶/(7 × 4200) ≈ 34.3°C → final temp ≈ 34°C

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Q.3 Medium Thermodynamics
A refrigerator operates with a COP (Coefficient of Performance) of 4 between temperatures 250 K and 350 K. What is the theoretical maximum COP possible?
A 2.5
B 3.5
C 4.0
D 5.0
Correct Answer:  A. 2.5
EXPLANATION

Theoretical maximum COP = T_cold/(T_hot - T_cold) = 250/(350-250) = 250/100 = 2.5

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Q.4 Medium Thermodynamics
An ideal gas undergoes an adiabatic process from state (P₁, V₁, T₁) to (P₂, V₂, T₂) with γ = 1.4. If volume increases by 50%, the temperature ratio T₂/T₁ is approximately:
A 0.65
B 0.73
C 0.82
D 0.91
Correct Answer:  B. 0.73
EXPLANATION

For adiabatic process: TV^(γ-1) = constant. T₁V₁^0.4 = T₂(1.5V₁)^0.4. T₂/T₁ = (1/1.5)^0.4 = 0.73^0.4 ≈ 0.73

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Q.5 Medium Thermodynamics
Two identical blocks at different temperatures are brought into thermal contact in an isolated system. Block A at 400 K and Block B at 300 K both have mass 1 kg and specific heat 400 J/kg·K. What is the change in entropy of the universe?
A 0 J/K
B 22.4 J/K
C 11.2 J/K
D 45.8 J/K
Correct Answer:  C. 11.2 J/K
EXPLANATION

At equilibrium: T_f = (400 + 300)/2 = 350 K. ΔS_A = m·c·ln(T_f/T_A) = 1×400×ln(350/400) = -56 J/K. ΔS_B = 1×400×ln(350/300) = 56.4 J/K. ΔS_total ≈ 11.2 J/K

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Q.6 Medium Thermodynamics
A system undergoes a cyclic process. The internal energy change over one complete cycle is ΔU. Which statement is correct?
A ΔU is always zero for any cyclic process
B ΔU depends only on the path taken, not the cycle
C Q = W for the complete cycle
D The entropy of the universe increases by ΔS
Correct Answer:  A. ΔU is always zero for any cyclic process
EXPLANATION

Internal energy is a state function, so for a cyclic process where the system returns to its initial state, ΔU = 0 always, regardless of the path.

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Q.7 Easy Thermodynamics
A gas expands isothermally from volume V₁ to 3V₁ at temperature T. If the initial pressure is P₁, what is the work done by the gas?
A P₁V₁ ln(3)
B 3P₁V₁
C P₁V₁/3
D P₁V₁
Correct Answer:  A. P₁V₁ ln(3)
EXPLANATION

For isothermal process: W = nRT ln(V_f/V_i) = P₁V₁ ln(3V₁/V₁) = P₁V₁ ln(3)

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Q.8 Easy Thermodynamics
Three moles of an ideal diatomic gas are heated at constant pressure from 300 K to 600 K. Calculate the heat absorbed by the gas. (R = 8.314 J/mol·K)
A 74,826 J
B 49,884 J
C 24,942 J
D 99,768 J
Correct Answer:  A. 74,826 J
EXPLANATION

For constant pressure: Q = n·Cp·ΔT. For diatomic gas, Cp = (7/2)R. Q = 3 × (7/2) × 8.314 × (600-300) = 3 × 3.5 × 8.314 × 300 = 26,194 × 2.85 ≈ 74,826 J

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Q.9 Easy Thermodynamics
A heat engine operates between two reservoirs at temperatures 500 K and 300 K. What is the maximum theoretical efficiency of this engine?
A 40%
B 60%
C 75%
D 85%
Correct Answer:  A. 40%
EXPLANATION

Maximum efficiency (Carnot efficiency) = 1 - (T_cold/T_hot) = 1 - (300/500) = 1 - 0.6 = 0.4 = 40%

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Q.10 Hard Thermodynamics
Which thermodynamic process results in maximum work extraction from an ideal gas expanding from the same initial to final states?
A Isobaric process
B Isothermal process
C Isochoric process
D Adiabatic process
Correct Answer:  B. Isothermal process
EXPLANATION

For expansion between the same P-V states, isothermal process produces maximum work because W = nRT ln(V_f/V_i) is maximum when temperature is highest throughout the process.

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