Govt. Exams
Entrance Exams
Theoretical maximum COP = T_cold/(T_hot - T_cold) = 250/(350-250) = 250/100 = 2.5
For adiabatic process: TV^(γ-1) = constant. T₁V₁^0.4 = T₂(1.5V₁)^0.4. T₂/T₁ = (1/1.5)^0.4 = 0.73^0.4 ≈ 0.73
At equilibrium: T_f = (400 + 300)/2 = 350 K. ΔS_A = m·c·ln(T_f/T_A) = 1×400×ln(350/400) = -56 J/K. ΔS_B = 1×400×ln(350/300) = 56.4 J/K. ΔS_total ≈ 11.2 J/K
Internal energy is a state function, so for a cyclic process where the system returns to its initial state, ΔU = 0 always, regardless of the path.
From first law: ΔU = Q - W. If both Q and W are positive, ΔU = Q - W could be positive, negative, or zero depending on whether Q > W, Q < W, or Q = W respectively.
ΔS = Q/T = (2260 × 1000)/373 = 2260000/373 ≈ 6061 J/K ≈ 6.1 kJ/K
For Carnot refrigerator: COP = T_c/(T_h - T_c) = 250/(300-250) = 250/50 = 5
Q = nC_vΔT. 5000 = 2 × (5/2) × 8.314 × ΔT. ΔT = 5000/(5 × 8.314) = 5000/41.57 ≈ 120.2 K. Final T = 300 + 120.2 ≈ 380 K
From PV² = constant: P₁V₁² = P₂V₂². P₂/P₁ = (V₁/V₂)² = (V/2V)² = 1/4
In a reversible process, total entropy change = 0. ΔS_system + ΔS_surroundings = 0. This is the definition of a reversible process.