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JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Topics in JEE Physics
Q.1 Medium Thermodynamics
A refrigerator operates with a COP (Coefficient of Performance) of 4 between temperatures 250 K and 350 K. What is the theoretical maximum COP possible?
A 2.5
B 3.5
C 4.0
D 5.0
Correct Answer:  A. 2.5
EXPLANATION

Theoretical maximum COP = T_cold/(T_hot - T_cold) = 250/(350-250) = 250/100 = 2.5

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Q.2 Medium Thermodynamics
An ideal gas undergoes an adiabatic process from state (P₁, V₁, T₁) to (P₂, V₂, T₂) with γ = 1.4. If volume increases by 50%, the temperature ratio T₂/T₁ is approximately:
A 0.65
B 0.73
C 0.82
D 0.91
Correct Answer:  B. 0.73
EXPLANATION

For adiabatic process: TV^(γ-1) = constant. T₁V₁^0.4 = T₂(1.5V₁)^0.4. T₂/T₁ = (1/1.5)^0.4 = 0.73^0.4 ≈ 0.73

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Q.3 Medium Thermodynamics
Two identical blocks at different temperatures are brought into thermal contact in an isolated system. Block A at 400 K and Block B at 300 K both have mass 1 kg and specific heat 400 J/kg·K. What is the change in entropy of the universe?
A 0 J/K
B 22.4 J/K
C 11.2 J/K
D 45.8 J/K
Correct Answer:  C. 11.2 J/K
EXPLANATION

At equilibrium: T_f = (400 + 300)/2 = 350 K. ΔS_A = m·c·ln(T_f/T_A) = 1×400×ln(350/400) = -56 J/K. ΔS_B = 1×400×ln(350/300) = 56.4 J/K. ΔS_total ≈ 11.2 J/K

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Q.4 Medium Thermodynamics
A system undergoes a cyclic process. The internal energy change over one complete cycle is ΔU. Which statement is correct?
A ΔU is always zero for any cyclic process
B ΔU depends only on the path taken, not the cycle
C Q = W for the complete cycle
D The entropy of the universe increases by ΔS
Correct Answer:  A. ΔU is always zero for any cyclic process
EXPLANATION

Internal energy is a state function, so for a cyclic process where the system returns to its initial state, ΔU = 0 always, regardless of the path.

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Q.5 Medium Thermodynamics
When a system undergoes a process where both Q and W are positive, which statement is true?
A Internal energy decreases
B Internal energy increases
C Internal energy may increase or decrease
D Internal energy remains constant
Correct Answer:  C. Internal energy may increase or decrease
EXPLANATION

From first law: ΔU = Q - W. If both Q and W are positive, ΔU = Q - W could be positive, negative, or zero depending on whether Q > W, Q < W, or Q = W respectively.

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Q.6 Medium Thermodynamics
A substance has a latent heat of vaporization of 2260 kJ/kg at 373 K. The entropy change during vaporization of 1 kg of water is approximately:
A 6.1 kJ/K
B 0.61 kJ/K
C 61 J/K
D 610 J/K
Correct Answer:  A. 6.1 kJ/K
EXPLANATION

ΔS = Q/T = (2260 × 1000)/373 = 2260000/373 ≈ 6061 J/K ≈ 6.1 kJ/K

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Q.7 Medium Thermodynamics
For a Carnot refrigerator operating between 250 K (cold reservoir) and 300 K (hot reservoir), the coefficient of performance (COP) is:
A 5
B 6
C 1.2
D 0.2
Correct Answer:  A. 5
EXPLANATION

For Carnot refrigerator: COP = T_c/(T_h - T_c) = 250/(300-250) = 250/50 = 5

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Q.8 Medium Thermodynamics
A thermally insulated container holds 2 moles of oxygen gas at 300 K. A heating element supplies 5000 J of heat to the gas. What is the final temperature? (C_v for O₂ = 5R/2, R = 8.314 J/mol·K)
A 360 K
B 420 K
C 380 K
D 400 K
Correct Answer:  C. 380 K
EXPLANATION

Q = nC_vΔT. 5000 = 2 × (5/2) × 8.314 × ΔT. ΔT = 5000/(5 × 8.314) = 5000/41.57 ≈ 120.2 K. Final T = 300 + 120.2 ≈ 380 K

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Q.9 Medium Thermodynamics
A gas undergoes a process where PV² = constant. If the gas expands from volume V to 2V, what is the ratio of final to initial pressure?
A 1/4
B 1/2
C 1/8
D 2
Correct Answer:  A. 1/4
EXPLANATION

From PV² = constant: P₁V₁² = P₂V₂². P₂/P₁ = (V₁/V₂)² = (V/2V)² = 1/4

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Q.10 Medium Thermodynamics
For a reversible isothermal process of an ideal gas, the entropy change of the universe is:
A Positive
B Negative
C Zero
D Equal to entropy change of surroundings
Correct Answer:  C. Zero
EXPLANATION

In a reversible process, total entropy change = 0. ΔS_system + ΔS_surroundings = 0. This is the definition of a reversible process.

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