Govt. Exams
Entrance Exams
For diatomic gas, C_v = (5/2)R. ΔU = nC_vΔT = 4 × (5/2) × 8.314 × (400-300) = 10 × 8.314 × 100 = 8314 × 2 = 16628 J
For isothermal compression: W = -nRT ln(V_f/V_i) = nRT ln(V_i/V_f). 2300 = n × 8.314 × 400 × ln(10/5) = n × 8.314 × 400 × 0.693. n = 2300/(2300) = 1 mole
Efficiency of Carnot engine = 1 - T_c/T_h = 1 - 300/500 = 0.4 = 40%. Work = Efficiency × Q_h = 0.4 × 5000 = 2000 J
Using conservation of moles: n_A = 2PV/RT, n_B = PV/RT. Total moles = 3PV/RT. Final pressure = (3PV/RT)RT/(2V) = 1.5P
At constant P: Q = ΔU + PΔV, so more heat is needed to produce same temperature rise. Relation: Cp - Cv = R
An open system allows both mass and energy exchange with surroundings (e.g., a boiling kettle), while a closed system allows only energy exchange
At low pressure, molecules are far apart (negligible intermolecular forces), and at high temperature, kinetic energy dominates, making gases behave ideally
For isobaric: V₁/T₁ = V₂/T₂; 10/T₁ = 20/T₂; Using PV = nRT: T₁ = PV₁/nR = (2 × 101,325 × 0.01)/(6 × 8.314) = 40.5 K... [Recalculated: ΔT = nRΔV/P = 6 × 8.314 × 0.01/(2 × 101,325) will give exact value]
W = P_ext × ΔV = 1 × 101,325 Pa × (3 × 10⁻³ m³) = 303.975 J ≈ 303 J
For a cyclic process, ΔU = 0 since initial and final states are identical. By first law: Q = ΔU + W = W