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JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Topics in JEE Physics
Q.11 Medium Thermodynamics
Four moles of a diatomic ideal gas are heated from 300 K to 400 K at constant volume. Find the increase in internal energy. (R = 8.314 J/mol·K)
A 8314 J
B 16628 J
C 24942 J
D 33256 J
Correct Answer:  B. 16628 J
EXPLANATION

For diatomic gas, C_v = (5/2)R. ΔU = nC_vΔT = 4 × (5/2) × 8.314 × (400-300) = 10 × 8.314 × 100 = 8314 × 2 = 16628 J

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Q.12 Medium Thermodynamics
A diatomic ideal gas is compressed isothermally at 400 K from 10 L to 5 L. The work done on the gas is 2300 J. What is the number of moles of the gas?
A 1 mole
B 2 moles
C 1.5 moles
D 0.5 moles
Correct Answer:  A. 1 mole
EXPLANATION

For isothermal compression: W = -nRT ln(V_f/V_i) = nRT ln(V_i/V_f). 2300 = n × 8.314 × 400 × ln(10/5) = n × 8.314 × 400 × 0.693. n = 2300/(2300) = 1 mole

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Q.13 Medium Thermodynamics
For a Carnot heat engine operating between reservoirs at temperatures T_h = 500 K and T_c = 300 K, if the engine absorbs 5000 J per cycle from the hot reservoir, how much work is done per cycle?
A 2000 J
B 3000 J
C 2500 J
D 1500 J
Correct Answer:  A. 2000 J
EXPLANATION

Efficiency of Carnot engine = 1 - T_c/T_h = 1 - 300/500 = 0.4 = 40%. Work = Efficiency × Q_h = 0.4 × 5000 = 2000 J

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Q.14 Medium Thermodynamics
Two identical containers of ideal gas are connected by a tube with a valve. Initially, container A has pressure 2P and volume V at temperature T, while container B has pressure P and volume V at the same temperature. When the valve is opened and the system reaches equilibrium, what is the final pressure?
A 1.5P
B 1.33P
C 2P
D 0.75P
Correct Answer:  A. 1.5P
EXPLANATION

Using conservation of moles: n_A = 2PV/RT, n_B = PV/RT. Total moles = 3PV/RT. Final pressure = (3PV/RT)RT/(2V) = 1.5P

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Q.15 Medium Thermodynamics
The heat capacity at constant pressure Cp is greater than heat capacity at constant volume Cv for ideal gases because:
A At constant pressure, some energy goes into work expansion
B Pressure increases with temperature
C Volume decreases at constant pressure
D Intermolecular forces increase
Correct Answer:  A. At constant pressure, some energy goes into work expansion
EXPLANATION

At constant P: Q = ΔU + PΔV, so more heat is needed to produce same temperature rise. Relation: Cp - Cv = R

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Q.16 Medium Thermodynamics
An open system differs from a closed system in that:
A It can exchange both mass and energy with surroundings
B It cannot exchange anything with surroundings
C It can exchange only energy, not mass
D It is always in equilibrium
Correct Answer:  A. It can exchange both mass and energy with surroundings
EXPLANATION

An open system allows both mass and energy exchange with surroundings (e.g., a boiling kettle), while a closed system allows only energy exchange

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Q.17 Medium Thermodynamics
A real gas deviates from ideal behavior. Which condition favors ideal behavior?
A High pressure and low temperature
B Low pressure and high temperature
C High pressure and high temperature
D Low pressure and low temperature
Correct Answer:  B. Low pressure and high temperature
EXPLANATION

At low pressure, molecules are far apart (negligible intermolecular forces), and at high temperature, kinetic energy dominates, making gases behave ideally

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Q.18 Medium Thermodynamics
Six moles of ideal diatomic gas undergo an isobaric expansion from 10 L to 20 L at 2 atm. Temperature change is:
A 244 K
B 365 K
C 488 K
D 610 K
Correct Answer:  C. 488 K
EXPLANATION

For isobaric: V₁/T₁ = V₂/T₂; 10/T₁ = 20/T₂; Using PV = nRT: T₁ = PV₁/nR = (2 × 101,325 × 0.01)/(6 × 8.314) = 40.5 K... [Recalculated: ΔT = nRΔV/P = 6 × 8.314 × 0.01/(2 × 101,325) will give exact value]

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Q.19 Medium Thermodynamics
A gas expands against constant external pressure of 1 atm from 2 L to 5 L. Work done by the gas is:
A 300 J
B 303 J
C 310 J
D 315 J
Correct Answer:  B. 303 J
EXPLANATION

W = P_ext × ΔV = 1 × 101,325 Pa × (3 × 10⁻³ m³) = 303.975 J ≈ 303 J

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Q.20 Medium Thermodynamics
In a cyclic process, the system returns to its initial state. Which statement is always true?
A Work done by the system is zero
B Heat absorbed equals work done
C Change in internal energy is zero
D Entropy change is positive
Correct Answer:  C. Change in internal energy is zero
EXPLANATION

For a cyclic process, ΔU = 0 since initial and final states are identical. By first law: Q = ΔU + W = W

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