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JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Topics in JEE Physics
Q.31 Medium Thermodynamics
Two identical blocks of metal at different temperatures are brought into thermal contact in an isolated system. The process is:
A Reversible and entropy of universe increases
B Reversible and entropy of universe remains constant
C Irreversible and entropy of universe increases
D Irreversible and entropy of universe remains constant
Correct Answer:  C. Irreversible and entropy of universe increases
EXPLANATION

Heat transfer between objects at different temperatures is irreversible. For an isolated system, ΔS_universe = ΔS_system > 0 (irreversible process), not equal to zero.

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Q.32 Medium Thermodynamics
One mole of an ideal monoatomic gas is heated at constant volume from 300 K to 600 K. The change in internal energy is (R = 8.314 J/mol·K):
A 12,471 J
B 24,942 J
C 37,413 J
D 6,235.5 J
Correct Answer:  A. 12,471 J
EXPLANATION

For monoatomic ideal gas, Cv = (3/2)R. ΔU = nCvΔT = 1 × (3/2) × 8.314 × (600 − 300) = (3/2) × 8.314 × 300 = 3,741 × 3.33 ≈ 12,471 J

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Q.33 Medium Thermodynamics
A refrigerator operates on a Carnot cycle between -10°C and 30°C. The coefficient of performance (COP) is approximately:
A 4.5
B 6.5
C 8.5
D 10.5
Correct Answer:  B. 6.5
EXPLANATION

COP = Tc/(Th - Tc) = 263/(303 - 263) = 263/40 ≈ 6.575 ≈ 6.5

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Q.34 Medium Thermodynamics
The molar heat capacity at constant pressure for a diatomic ideal gas is:
A (3/2)R
B (5/2)R
C (7/2)R
D (9/2)R
Correct Answer:  C. (7/2)R
EXPLANATION

For diatomic gas: Cv = (5/2)R. Using Cp = Cv + R, we get Cp = (5/2)R + R = (7/2)R

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Q.35 Medium Thermodynamics
A cylinder with a movable piston contains 2 moles of ideal gas at 300 K and 1 atm. When heated at constant pressure to 600 K, what is the work done by the gas? (R = 8.314 J/mol·K)
A 2492 J
B 4984 J
C 9968 J
D 1246 J
Correct Answer:  B. 4984 J
EXPLANATION

For isobaric process: W = nRΔT = 2 × 8.314 × (600 - 300) = 2 × 8.314 × 300 = 4988.4 ≈ 4984 J

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Q.36 Medium Thermodynamics
Which process would result in the maximum work output from an ideal gas expansion between two fixed pressures?
A Isothermal process
B Isobaric process
C Isochoric process
D Adiabatic process
Correct Answer:  A. Isothermal process
EXPLANATION

For expansion between fixed initial and final states, isothermal process yields maximum work because the gas maintains maximum pressure throughout the expansion compared to adiabatic or other processes.

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Q.37 Medium Thermodynamics
The entropy change for a reversible isothermal process is given by:
A ΔS = Q/T
B ΔS = nR ln(Vf/Vi)
C Both A and B
D ΔS = nCv ln(Tf/Ti)
Correct Answer:  C. Both A and B
EXPLANATION

For reversible isothermal process: ΔS = Q/T = nR ln(Vf/Vi) since Q = nRT ln(Vf/Vi) for ideal gas isothermal expansion.

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Q.38 Medium Thermodynamics
A heat engine absorbs 1000 J of heat and rejects 600 J to the cold reservoir in one cycle. What is its efficiency?
A 40%
B 60%
C 37.5%
D 62.5%
Correct Answer:  A. 40%
EXPLANATION

Efficiency η = (Qh - Qc)/Qh = (1000 - 600)/1000 = 400/1000 = 0.40 = 40%

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Q.39 Medium Thermodynamics
Two samples of the same ideal gas at the same temperature have volumes V and 2V respectively. The ratio of their internal energies is:
A 1:2
B 1:1
C 2:1
D Cannot be determined
Correct Answer:  D. Cannot be determined
EXPLANATION

Internal energy U = nCvT. Without knowing the number of moles in each sample, the ratio cannot be determined. Same temperature doesn't mean same internal energy.

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Q.40 Medium Thermodynamics
For a diatomic ideal gas undergoing an isothermal process, which quantity remains constant?
A Pressure
B Volume
C Internal energy
D Density
Correct Answer:  C. Internal energy
EXPLANATION

In an isothermal process, temperature is constant. For an ideal gas, internal energy depends only on temperature, so ΔU = 0. Pressure and volume change according to PV = constant.

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