Home Subjects JEE Physics Thermodynamics

JEE Physics
Thermodynamics

Physics questions for JEE Main — Mechanics, Electrostatics, Optics, Modern Physics.

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Difficulty: All Easy Medium Hard 41–50 of 50
Topics in JEE Physics
Q.41 Medium Thermodynamics
During an isobaric expansion of an ideal gas, the work done by the gas is 400 J. If pressure is constant at 2 atm, what is the change in volume? (1 atm = 101325 Pa)
A 0.002 m³
B 0.00197 m³
C 0.002 m³
D 0.001 m³
Correct Answer:  B. 0.00197 m³
EXPLANATION

W = PΔV. Here W = 400 J, P = 2 × 101325 = 202650 Pa. So ΔV = W/P = 400/202650 ≈ 0.00197 m³

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Q.42 Medium Thermodynamics
In an expansion process, a gas does 500 J of work and absorbs 300 J of heat. What is the change in internal energy?
A ΔU = -200 J
B ΔU = 200 J
C ΔU = -800 J
D ΔU = 800 J
Correct Answer:  A. ΔU = -200 J
EXPLANATION

Using first law: ΔU = Q - W = 300 - 500 = -200 J (internal energy decreases)

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Q.43 Medium Thermodynamics
For a van der Waals gas, which statement is correct?
A It accounts for molecular volume and intermolecular forces
B It is identical to ideal gas behavior at high pressures
C It has no internal energy dependence on volume
D It violates the first law of thermodynamics
Correct Answer:  A. It accounts for molecular volume and intermolecular forces
EXPLANATION

Van der Waals equation (P + a/V²)(V - b) = RT accounts for molecular volume (b term) and intermolecular attractive forces (a term)

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Q.44 Medium Thermodynamics
A reversible cycle absorbs 100 J at 400 K and rejects heat at 300 K. What is the minimum heat rejected?
A Q_c = 75 J
B Q_c = 50 J
C Q_c = 33.3 J
D Q_c = 25 J
Correct Answer:  A. Q_c = 75 J
EXPLANATION

For reversible cycle: Q_h/T_h = Q_c/T_c. 100/400 = Q_c/300. Q_c = (100 × 300)/400 = 75 J

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Q.45 Medium Thermodynamics
A gas expands isothermally from 1 L to 10 L against a constant external pressure of 1 atm. What is the work done? (1 L·atm = 101.325 J)
A W = 910.125 J
B W = 1013.25 J
C W = 808.6 J
D W = 1114.6 J
Correct Answer:  A. W = 910.125 J
EXPLANATION

For isothermal expansion against constant pressure: W = PₑₓₜΔV = 1 × (10-1) = 9 L·atm = 9 × 101.325 = 910.125 J

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Q.46 Medium Thermodynamics
Which process is represented by PVⁿ = constant?
A Isothermal (n=1)
B Adiabatic (n=γ)
C Polytropic (any n)
D All of the above
Correct Answer:  D. All of the above
EXPLANATION

The polytropic equation PVⁿ = constant covers isothermal (n=1), adiabatic (n=γ), isobaric (n=0), and isochoric (n=∞) processes as special cases

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Q.47 Medium Thermodynamics
In an isobaric process, 5 moles of a monoatomic ideal gas are heated from 300 K to 400 K. What is the heat supplied? (R = 8.314 J/(mol·K))
A Q = 20.785 kJ
B Q = 41.57 kJ
C Q = 62.355 kJ
D Q = 31.178 kJ
Correct Answer:  C. Q = 62.355 kJ
EXPLANATION

For isobaric process: Q = nCₚΔT. For monoatomic gas, Cₚ = (5/2)R. Q = 5 × (5/2) × 8.314 × 100 = 62.355 kJ

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Q.48 Medium Thermodynamics
A cyclic process consists of two isothermal and two adiabatic processes (Carnot cycle). What is true about the heat exchanges?
A Heat is exchanged in both isothermal processes only
B Heat is exchanged in adiabatic processes
C Net heat exchange is always zero
D Heat exchange is equal in both isothermal processes
Correct Answer:  A. Heat is exchanged in both isothermal processes only
EXPLANATION

In Carnot cycle, isothermal processes involve heat exchange with reservoirs (Q₁ at hot reservoir, Q₂ at cold reservoir), while adiabatic processes have no heat exchange (Q=0)

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Q.49 Medium Thermodynamics
In an adiabatic process with a diatomic ideal gas (γ = 1.4), if the initial temperature is 300 K and volume increases by factor of 2, what is the final temperature?
A T₂ = 178.9 K
B T₂ = 212.1 K
C T₂ = 195.7 K
D T₂ = 223.4 K
Correct Answer:  A. T₂ = 178.9 K
EXPLANATION

For adiabatic process: TVγ⁻¹ = constant. T₁V₁^(γ-1) = T₂V₂^(γ-1). 300 × 1^0.4 = T₂ × 2^0.4. T₂ = 300/2^0.4 = 300/1.6818 = 178.9 K

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Q.50 Medium Thermodynamics
A gas undergoes an isothermal process at 300 K. If the initial volume is 2 L and final volume is 5 L, what is the work done by the gas? (Take R = 8.314 J/(mol·K), n = 1 mol)
A W = 2.74 kJ
B W = 3.04 kJ
C W = 2.50 kJ
D W = 1.98 kJ
Correct Answer:  B. W = 3.04 kJ
EXPLANATION

For isothermal process: W = nRT ln(Vf/Vi) = 1 × 8.314 × 300 × ln(5/2) = 2494.2 × 1.609 = 3.04 kJ

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