Govt. Exams
Entrance Exams
W = PΔV. Here W = 400 J, P = 2 × 101325 = 202650 Pa. So ΔV = W/P = 400/202650 ≈ 0.00197 m³
Using first law: ΔU = Q - W = 300 - 500 = -200 J (internal energy decreases)
Van der Waals equation (P + a/V²)(V - b) = RT accounts for molecular volume (b term) and intermolecular attractive forces (a term)
For reversible cycle: Q_h/T_h = Q_c/T_c. 100/400 = Q_c/300. Q_c = (100 × 300)/400 = 75 J
For isothermal expansion against constant pressure: W = PₑₓₜΔV = 1 × (10-1) = 9 L·atm = 9 × 101.325 = 910.125 J
The polytropic equation PVⁿ = constant covers isothermal (n=1), adiabatic (n=γ), isobaric (n=0), and isochoric (n=∞) processes as special cases
For isobaric process: Q = nCₚΔT. For monoatomic gas, Cₚ = (5/2)R. Q = 5 × (5/2) × 8.314 × 100 = 62.355 kJ
In Carnot cycle, isothermal processes involve heat exchange with reservoirs (Q₁ at hot reservoir, Q₂ at cold reservoir), while adiabatic processes have no heat exchange (Q=0)
For adiabatic process: TVγ⁻¹ = constant. T₁V₁^(γ-1) = T₂V₂^(γ-1). 300 × 1^0.4 = T₂ × 2^0.4. T₂ = 300/2^0.4 = 300/1.6818 = 178.9 K
For isothermal process: W = nRT ln(Vf/Vi) = 1 × 8.314 × 300 × ln(5/2) = 2494.2 × 1.609 = 3.04 kJ