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Chemical Engineering

Process design, thermodynamics, reactions

247 Q 5 Topics Take Mock Test
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Difficulty: All Easy Medium Hard 61–70 of 247
Topics in Chemical Engineering
In a tubular reactor with axial dispersion, increasing the Peclet number (Pe) results in:
A RTD approaching that of an ideal PFR
B RTD approaching that of a CSTR
C No change in conversion
D Increased axial mixing
Correct Answer:  A. RTD approaching that of an ideal PFR
EXPLANATION

Peclet number Pe = uL/D. High Pe means low diffusion relative to convection, approaching ideal PFR behavior with narrow RTD.

Test
The mean residence time in a reactor can be calculated from RTD data using:
A τ = ∫₀^∞ t·E(t)dt
B τ = ∫₀^∞ E(t)dt
C τ = V/Q (definition)
D Both A and C are correct
Correct Answer:  D. Both A and C are correct
EXPLANATION

Both equations are valid: the integral formulation and the volumetric flow definition give the same mean residence time.

Test
In a membrane reactor for an equilibrium-limited reaction, what is the primary advantage?
A Increased pressure drop
B Selective removal of products shifts equilibrium forward, increasing conversion
C Reduced capital cost
D Simplified heat management
Correct Answer:  B. Selective removal of products shifts equilibrium forward, increasing conversion
EXPLANATION

By selectively removing product through the membrane, the equilibrium constant expression is displaced, allowing conversion beyond the thermodynamic limit.

Test
Which reactor configuration would be best suited for a fast, highly exothermic reaction where precise temperature control is critical?
A Batch reactor with mechanical agitation
B Semi-batch reactor with one reactant fed slowly
C Tubular reactor with jacket cooling
D CSTR with recycled cold feed
Correct Answer:  B. Semi-batch reactor with one reactant fed slowly
EXPLANATION

Semi-batch allows controlled feeding of reactants, limiting instantaneous heat generation while maintaining good mixing and temperature control.

Test
In a fixed-bed catalytic reactor, what is the primary cause of catalyst deactivation by sintering?
A Chemical reaction between catalyst and reactants
B Migration and agglomeration of metal particles at elevated temperatures
C Accumulation of by-products
D Loss of active sites due to oxidation
Correct Answer:  B. Migration and agglomeration of metal particles at elevated temperatures
EXPLANATION

Sintering involves migration of metal atoms on the catalyst surface, leading to agglomeration and reduction of active surface area, particularly at high temperatures.

Test
A series of 3 identical CSTRs in cascade is used to process a first-order reaction with overall conversion X = 90%. Which statement is true?
A The conversion in each reactor is 30%
B The pressure drop increases linearly across reactors
C The concentration decreases exponentially along the cascade
D The residence time in each reactor must be doubled compared to a single CSTR
Correct Answer:  C. The concentration decreases exponentially along the cascade
EXPLANATION

For equal volume CSTRs in series processing first-order reaction: C = C₀/(1+kτ)ⁿ, showing exponential decrease in concentration.

Test
In a semi-batch reactor where reactant A is fed continuously to a batch of reactant B, which advantage is realized?
A Reduced heat generation rate compared to adding all A at once
B Increased overall conversion by 50%
C Elimination of side reactions completely
D No cooling requirement needed
Correct Answer:  A. Reduced heat generation rate compared to adding all A at once
EXPLANATION

Continuous feeding of A reduces the instantaneous reaction rate and heat generation, allowing better temperature control and potentially reducing side reactions.

Test
For a reversible reaction A ⇌ B with equilibrium constant Ke = 4, what is the maximum theoretical conversion in a batch reactor at equilibrium?
A 50%
B 80%
C 66.7%
D 33.3%
Correct Answer:  B. 80%
EXPLANATION

At equilibrium: Ke = [B]/[A] = 4. If initial [A]₀ = C, then at equilibrium: 4 = X/(1-X), solving X = 0.8 or 80%

Test
A CSTR operating at steady state processes an exothermic reaction. If the inlet temperature increases by 10°C while maintaining constant coolant flow rate, which parameter is most likely to increase?
A Reactor volume required
B Conversion
C Reactor residence time
D Heat removal capacity of coolant
Correct Answer:  B. Conversion
EXPLANATION

Higher inlet temperature increases reaction rate (via Arrhenius equation) in an exothermic reaction, leading to higher conversion. Heat removal capacity depends on coolant flow and ΔT.

Test
In a plug flow reactor (PFR) processing a first-order irreversible reaction with rate constant k = 0.5 min⁻¹, what is the space-time (τ) required to achieve 80% conversion?
A 3.22 minutes
B 2.89 minutes
C 4.15 minutes
D 1.61 minutes
Correct Answer:  A. 3.22 minutes
EXPLANATION

For first-order reaction in PFR: τ = (1/k)ln(1/(1-X)) = (1/0.5)ln(1/0.2) = 2 × ln(5) = 2 × 1.609 = 3.22 minutes

Test
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